Gothel’s view of men seems to be as tools she can use so she might not be a lesbian but she’s not very man friendly. Also she’s not got a love interest which seems to be one of the reasons for making Elsa a lesbian so why not make Gothel one too?
I see what you’re saying, but I don’t think she’s friendly to anyone–male or female (or animal or vegetable or mineral).
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"He was a lot of things to me" "The only conclusion was love"